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Tytuł pozycji:

Sectrofluorometric characterisation of the lubricate oil

Exploitive features of lubricate oils are externalised by various physical and chemical parameters (for example temperature dependencies of density and viscosity, ignition point or water content). On the other hand it is well-known that fluorescence spectra of various types of crude oils and their derivatives are strongly differ from each other. It is reasonable thesis, that exploitive features of oil may be related to transformations of light inside the oil. Therefore, despite of that fact light transformations strongly depend on chemical composition of oil (especially from the content of cyclic and polycyclic molecules). No one can exclude, that physical conditions are for fluorescence processes closely related to changes of physical and chemical properties of oil (and consequently to exploitive features) as well as to newly arising compounds and intrusions (for example metals, caused by contact with various engine elements). The paper presents spectra of fluorescence of exemplary lubricate oil (Marinol) in various configurations, namely: emission spectrum for individual excitation wavelength, excitation spectrum for single emission wavelength, excitation-emission spectrum, synchronous fluorescence spectroscopy and total synchronous fluorescence spectroscopy. Dynamic structures of those spectra gives reason to conclude that shapes of fluorescence spectra may be controlled by exploitive features of oils.

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