Tytuł pozycji:
Synthesis and Characterization of 5,10,15,20-Tetra-(4-decanoyloxyphenyl)porphyrin and Transition Metal Complexes
Transition metal complexes of 5,10,15,20-tetra-(4-decanoyloxyphenyl)porphyrin TDPPM [M = Mn, Fe, Co, Ni, Cu, Zn; TDPPH2 = 5,10,15,20-tetra-(4-decanoyloxyphenyl)porphyrin] have been synthesized and characterized by UV-Vis, IR photoacoustic, 1HNMR spectroscopy, elemental analyses, molar conductivity and differential scanning calorimetry (DSC). The ligand and its Zn complex have liquid crystalline behavior. According to the DSC thermogram the Zn complex exhibits a low phase transition temperature at –8.987 graduateC and a wide mesophase range at 175graduateC.