Polimery oraz makrocząsteczki posiadające podstawnik pentafluorosulfanylowy, -SF5 : synteza, struktura, właściwości i zastosowanie

The pentafluorosulfanyl (-SF5) moiety is a lesser known and underutilized functional group that displays high electronegativity, chemical and thermal stability, and low surface energy, among other useful properties. As a substituent it is known for almost 60 years, however practical application of the unique -SF5 group in various areas of chemistry has only recently picked up, mostly due to longstanding challenges associated with its synthetic accessibility. Most of the latest attention involving the use of -SF5 has been in medicinal chemistry, but it has also started to feature much more frequently in functional materials design, especially in the area of optoelectronic materials. This review will describe polymers and macromolecules containing -SF5 substituent which has been introduced mainly at the monomer stage.

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Opracowanie rekordu ze środków MNiSW, umowa Nr 461252 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2020).