Tytuł pozycji:
Polynuclear chain complexes of ruthenium(II,III) pivalate dimers linked by 2,5-dimethyl-N,N'-dicyanobenzoquinonediimine, 1,4-benzoquinone, and 1,4-naphthoquinone
- Tytuł:
-
Polynuclear chain complexes of ruthenium(II,III) pivalate dimers linked by 2,5-dimethyl-N,N'-dicyanobenzoquinonediimine, 1,4-benzoquinone, and 1,4-naphthoquinone
- Autorzy:
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Yoshioka, D.
Hanada, M.
Mikuriya, M.
Hiromitsu, I.
- Data publikacji:
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2005
- Słowa kluczowe:
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Ru(II, III) dimer
dicyanobenzoquinonediimine
p-quinones
polymer complexes
- Język:
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angielski
- Dostawca treści:
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BazTech
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Przejdź do źródła Link otwiera się w nowym oknie
Reactions of ruthenium(II,III) pivalate dimer with 2,5-dimethyl-N,N'- dicyanobenzoquinonediimine (2,5-dmdcnqi), 1,4-benzoquinone (1,4-bq), and 1,4- naphthoquinone (1,4-nq) gave polynuclear chain complexes, [Ru2(O2CCMe3)4(L)]nXn, L = 2,5-dmdcnqi, 1,4-bq, and 1,4-nq and X = BF4- and PF6-. It was shown that a weak antiferromagnetic interaction (J = -0.15 cm-1) operates between Ru(II,III) dimers for the 2,5- dmdcnqui complex.
