Tytuł pozycji:
Sythesis and characterization of novel copper (II) complexes of dehydroacetic acid thiosemicarrbazone
Dehydroacetic acid thiosemicarbazone and its copper(II) complexes have been synthesized and characterized by elemental analyses, IR, VIS-UV, magnetic susceptibility, conductivity, DTA and ESR spectra. Molar conductance indicates that the complexes are non-electrolytes except for [Cu(H2L)]SO4×2H20. The ESR spectra of the complexes show axial type symmetry with gII>g1>2.00, indicating dx2-y2 ground state with significant covalent bond character.