Synthesis of Diphenylphosphine Oxide and Diethyl Phosphonate with 4-Dimethylsila-2-hexen-6-ol Moiety

Szczegóły
Abstrakt

Tytuł:: Synthesis of Diphenylphosphine Oxide and Diethyl Phosphonate with 4-Dimethylsila-2-hexen-6-ol Moiety
Autorzy:: Gawdzik, B.
Wawrzeńczyk, C.
Data publikacji:: 2005
Słowa kluczowe:: 3-(2-hydroxyethyldimethylsila)-2-propen-1-yldiphenylphosphine oxide
diethyl 3-(2-hydroxyethyldimethylsila)-2-propen-1-ylphosphonate
Arbusov reaction
hydrosilylation
Horner-Wittig reaction
phosphorus
silicon
Język:: angielski
Dostawca treści:: BazTech
: Artykuł

Przejdź do źródła

Two reagents useful for the Horner-Wittig or Wadshworth-Emmons reaction: 3-(2- hydroxyethyldimethylsila)-2-propen-1-yldiphenylphosphine oxide (5a) and diethyl 3-(2-hydroxyethyldimethylsila)-2-propen-1-ylphosphonate (5b) were synthesized from propargyl chloride and dimethylchlorosilane. The usefulness of phosphine oxide was demonstrated in the olefination reactions of benzaldehyde and hexanal.

Informacja

Synthesis of Diphenylphosphine Oxide and Diethyl Phosphonate with 4-Dimethylsila-2-hexen-6-ol Moiety