Formation and Thermodynamic Analyses of Inclusions in Ti-Containing Steel Weld Metals with Different Al Contents

Ti-containing steel weld metals with Al contents of 0.01-0.085% were prepared. The effects of Al contents on the inclusions evolution were investigated by means of thermodynamic calculations coupled with electron probe micro-analyses and transmission electron microscopy. The results show that the inclusions in the 0.01% Al weld metal are mainly composed of ilmenite withsome amounts of (Mn-Si-Al)-oxide and titanial_spinel. When Al content is increased up to 0.035%, a more amount of corundum and a small amount of pseudobrookite are formed. In 0.085% Al weld metal, the (Mn-Si-Al)-oxide disappears completely, and the inclusions contain a substantial amount of corundum, in addition to a minimal amount of pseudobrookite. Ti3O5, MnTi2O4 and MnTiO3 are the primary constituents of pseudobrookite, titanial_spinel and ilmenite, respectively. Titanial_spinel and ilmenite have higher amounts of Mn, but lower Ti levels compared with pseudobrookite. In the case of presence of a considerable amountsof titanial_spinel and ilmenite, Mn-depleted zone is formed in matrix around the inclusions.

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1. This work was financially supported by a Project of Education Department of Liaoning Province (grant no. L2016132).

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2. Opracowanie rekordu ze środków MNiSW, umowa Nr 461252 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2021).