Tytuł pozycji:
Synthesis and Property of 1,4-Diamino-3,6- dinitropyrazolo[4,3-c]pyrazole and Its Derivatives
- Tytuł:
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Synthesis and Property of 1,4-Diamino-3,6- dinitropyrazolo[4,3-c]pyrazole and Its Derivatives
- Autorzy:
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Li, Y.-N.
Wang, B.-Z.
Shu, Y.-J.
Zhang, S.-Y.
Lian, P.
- Data publikacji:
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2016
- Słowa kluczowe:
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3,6-dinitropyrazolo[4,3-c]pyrazole (DNPP)
1,4-diamino-3,6- dinitropyrazolo[4,3-c]pyrazole (DADNP)
4,4’-(triaz-1-ene-1,3-diyl)bis(1- amine-3,6-dinitropyrazolo[4,3-c]pyrazole) (TBADNP)
N-amination reaction
synthesis
property
- Język:
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angielski
- Dostawca treści:
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BazTech
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A synthetic procedure has been developed for the synthesis of 1,4-diamino- 3,6-dinitropyrazolo[4,3-c]pyrazole (DADNP) via N-amination reaction. Its derivatives, 4,4’-(triaz-1-ene-1,3-diyl)bis(1-amine-3,6-dinitropyrazolo[4,3-c] pyrazole) (TBADNP) and 1,4-dinitramino-3,6-dinitropyrazolo[4,3-c]pyrazole (DNADNP), were first designed and synthesized by the diazotization and nitrification of amino group, and their structures were characterized by IR, 1H NMR, 13C NMR, elementary analysis and MS. The thermal properties of target compounds were studied by means of differential scanning calorimetry (DSC) and thermogravimetry (TG). The thermal decomposition peak temperatures of DADNP, TBADNP and DNADNP are 227, 236 and 288 °C, respectively. Results show that the derivatives of 1,4-diamino-3,6-dinitropyrazolo[4,3-c]pyrazole have better thermal stability.
Opracowanie ze środków MNiSW w ramach umowy 812/P-DUN/2016 na działalność upowszechniającą naukę.
