Reductive Elimination from Sterically Encumbered Ni−Polypyridine Complexes

Szczegóły
Opis

Tytuł:: Reductive Elimination from Sterically Encumbered Ni−Polypyridine Complexes
Autorzy:: Ton, Stephanie J.
Day, Craig S.
McGuire, Ryan T.
Martin, Ruben
Foroutan-Nejad, Cina
Data publikacji:: 2022
Wydawca:: American Chemical Society
Język:: angielski
ISBN, ISSN:: 02767333
Prawa:: http://creativecommons.org/licenses/by/4.0/
Linki:: https://open.icm.edu.pl/handle/123456789/21811 Link otwiera się w nowym oknie
Dostawca treści:: Repozytorium Centrum Otwartej Nauki
: Artykuł

Przejdź do źródła

ICIQ and MICIU (PID2021-133801NB-I00) European Union’s Horizon 2020 Programme under Marie Curie PREBIST Grant Agreement 754558 National Science Centre, Poland (2020/39/B/ST4/02022)

Herein we disclose the synthesis of sterically encumbered dialkylnickel(II) complexes bearing 2,9-dimethyl-1,10-phenanthroline ligands. A comparison with their unsubstituted analogues by both X-ray crystallography and theoretical calculations revealed significant distortions in their molecular structures. Eyring plots along with stoichiometric and photoexcitation studies revealed that sterically encumbered dialkylnickel(II) complexes enable facile C(sp3)–C(sp3) reductive elimination, thus offering an improved understanding of Ni catalysis.

Informacja

Reductive Elimination from Sterically Encumbered Ni−Polypyridine Complexes